Need An Special ORDER BY Clause Query

Table:Columns
UsersList:UserID, UserName, Country

I need a query which select all the rows from the above mentioned table with all fields
But
The order the rows is
First all the users from "Pakistan"
Second all the users from rest of the countries except "Pakistan" in ascending order

So the query first return all the users from Pakistan and the the users from rest of the world in ascending order.

Forexample,

1, ABC, USA
2, XYZ, Saudi Arabia
3, LMN, Pakistan
4, TQR, India
5, PTR, Afghanistan

then the query returns.

3, LMN, Pakistan
5, PTR, Afghanistan
4, TQR, India
2, XYZ, Saudi Arabia
1, ABC, USA